Alkoxyamines represent a versatile class of compounds central to the advancement of controlled radical polymerisation. By undergoing a reversible homolytic cleavage of the C–ON bond, they generate a ...
Redox-active but highly durable nitroxide radicals, that is, 2,2,6,6-tetramethylpiperidinyl-4-oxy (TEMPO), enabled direct electrospinning of radical-containing polymers without additional processing ...
Chemists have plotted a synthetic route to a new class of persistent nitroxide radicals by taking advantage of the synergistic action of an acid-base species known as a frustrated Lewis pair (FLP) to ...
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